Is fracture of oxide glasses ductile at the nanometer scale? · revision history
Revision 2
Accepted · core change · record
Changes against revision 1:
- Title · changed
- Revision 1: Is fracture of oxide glasses ductile at the nanometer scale
- Revision 2: Is fracture of oxide glasses ductile at the nanometer scale?
- Plain
- Window glass breaks in a brittle way, but microscope images in 2003 suggested that tiny cavities open ahead of a slowly moving crack, as in a metal. Later work found no such cavities, and whether glass is ductile at the nanometer scale is disputed.
- Precise · changed · core
- Revision 1: For slow stress-corrosion cracks in silica and aluminosilicate glasses, determine whether crack advance involves a plastic process zone with nanocavities of size about 1e-6 cm ahead of the tip, or atom-by-atom bond rupture with a process zone of a few bond lengths. An answer gives the process-zone size and the fraction of fracture energy dissipated plastically, from in situ imaging or matched fracture-surface analysis and simulations with reliable silica potentials.
- Revision 2: For slow stress-corrosion cracks in silica and aluminosilicate glasses, determine whether crack advance involves a plastic process zone with nanocavities of size about $10^{-6}$ cm ahead of the tip, or atom-by-atom bond rupture with a process zone of a few bond lengths. An answer gives the process-zone size and the fraction of fracture energy dissipated plastically, from in situ imaging or matched fracture-surface analysis and simulations with reliable silica potentials.
- Settled by
- In situ, nanometer-resolution imaging of a propagating crack tip in silica, or matched-surface topography with sub-nanometer resolution, consistent with large-scale atomistic simulations.
- Kind
- well-posed
- Answer type
- yes-no
- References
- (empty)
- Literature status
- contested
- Status note
- Nanocavities reported by atomic force microscopy in 2003 (Celarie et al., Phys. Rev. Lett., https://doi.org/10.1103/PhysRevLett.90.075504) were not found by matched fracture-surface analysis in 2004 (Guin and Wiederhorn, https://doi.org/10.1103/PhysRevLett.92.215502).
- Posed since
- 2003
Decisions
- Accept · 2026-10-15 · record