Magnitude of the electric field at water-hydrophobic interfaces · revision history
Revision 2
Accepted · core change · record
Changes against revision 1:
- Title
- Magnitude of the electric field at water-hydrophobic interfaces
- Plain
- Some explanations of fast droplet chemistry need very strong electric fields right at the water surface. Measuring how strong these fields really are would test those explanations.
- Precise · changed · core
- Revision 1: Determine the mean electric field projected on a probe bond at the water-air and water-oil interfaces at 300 K, from vibrational Stark shifts of interface-specific probes and from ab initio molecular dynamics, and compare with bulk water. The answer is the field magnitude (reported values range up to about $3e4\,\mathrm{statvolt}/\mathrm{cm}$) with its spatial profile across the interface.
- Revision 2: Determine the mean electric field projected on a probe bond at the water-air and water-oil interfaces at 300 K, from vibrational Stark shifts of interface-specific probes and from ab initio molecular dynamics, and compare with bulk water. The answer is the field magnitude (reported values range up to about $3 \times 10^{4}\,\mathrm{statvolt}/\mathrm{cm}$) with its spatial profile across the interface.
- Settled by
- Surface-selective vibrational Stark spectroscopy calibrated against bulk and ab initio simulations with the same probe.
- Kind
- well-posed
- Answer type
- value
- References
- (empty)
- Literature status
- open
- Status note
- (empty)
- Posed since
- (empty)
Decisions
- Accept · 2026-10-15 · record