What atoms tunnel in the two-level systems of amorphous silica? · revision history

Revision 2

Accepted · core change · record

Changes against revision 1:

Title
What atoms tunnel in the two-level systems of amorphous silica?
Plain
The tunneling model assumes small groups of atoms that flip between two nearly equal positions. Which atoms move, and how many, has never been identified in any glass.
Precise · changed · core
Revision 1: For amorphous SiO2 (and a-Si, a-Al2O3), identify the atomic configurations that form tunneling two-level systems with energies below $\sim 1e-4\,\mathrm{eV}$ ($\sim 1\,\mathrm{K}$), and reproduce their measured density of states $P$, deformation potential $\gamma \sim 0.5-1\,\mathrm{eV}$, electric dipole moments and isotope dependence.
Revision 2: For amorphous $\mathrm{SiO_2}$ (and a-Si, a-Al2O3), identify the atomic configurations that form tunneling two-level systems with energies below $\sim 10^{-4}\,\mathrm{eV}$ ($\sim 1\,\mathrm{K}$), and reproduce their measured density of states $P$, deformation potential $\gamma \sim 0.5-1\,\mathrm{eV}$, electric dipole moments and isotope dependence.
Settled by
Atomistic simulation of a realistically quenched glass that finds tunneling double wells with the measured $P$, $\gamma$ and dipole moments, confirmed by an isotope-substitution or strain-spectroscopy experiment.
Kind
well-posed
Answer type
identification
References
(empty)
Literature status
open
Status note
(empty)
Posed since
(empty)

Decisions