Excess charge of molecules bounded by a constant per nucleus · revision history
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- Title
- Excess charge of molecules bounded by a constant per nucleus
- Plain
- A molecule with several nuclei can also hold extra electrons. Show that the number of extra electrons is at most a fixed constant times the number of nuclei, whatever the nuclear charges and positions.
- Precise
- For $K$ static nuclei with charges $Z_1, ..., Z_K$ at positions $R_1, ..., R_K$, $Z_{\mathrm{tot}} = \sum_k Z_k$, and $N$ electrons with Coulomb interactions, let $N_c$ be the largest N for which the electronic ground state is bound. Prove $N_c \le Z_{\mathrm{tot}} + C K$ with C independent of the Z_k, R_k and K, or give a counterexample family.
- Settled by
- A proof of the bound uniform in nuclear charges and positions, or an explicit configuration violating it.
- Kind
- well-posed
- Answer type
- proof
- References
- (empty)
- Literature status
- open
- Status note
- Lieb's 1984 bound $N_c < 2 Z_{\mathrm{tot}} + K$ holds for all nuclear positions.
- Posed since
- 1984